835912-59-9Relevant academic research and scientific papers
An unusual cis-phosphonodithioato Pd(II) complex in an extensive hydrogen bonding 3D network
Carla Aragoni, Maria,Arca, Massimiliano,Demartin, Francesco,Devillanova, Francesco A.,Isaia, Francesco,Lippolis, Vito,Verani, Gaetano
, p. 213 - 216 (2005)
The one-pot self-assembly of an extended network of hydrogen bondings involving a cis-Pd-phosphonodithioato complex, ethylenediamine and water is presented. The P-N bond hydrolysis of the 4-methoxyphenyl-ammoniumethylamido- phosphonodithioato ligand on complexation to PdII leads to the first example of a Pd-phosphonodithioato complex in a cis configuration, stabilised in the solid state by an extended network of hydrogen bondings involving the released ethylenediamine and a water molecule.
