83622-71-3Relevant academic research and scientific papers
Miscellaneous reactions of some tris(trimethylsilyl)methylsilicon compounds
Eaborn, Colin,Fattah, Faraedan A.
, p. 1 - 8 (2007/10/02)
TsiSiMe2I (Tsi = (Me3Si)3C) gives TsiSiMe2OMe on treatment with AgBF4 in MeOH but some TsiSiMe2F if an excess of CsF is also present.The triflates TsiSiMe2OSO2CF3 and (Me3Si)2C(SiMePh2)(SiMe2OSO2CF3) react with alkali metal salts MX to give the correspond
SOME HIGHLY STERICALLY HINDERED ORGANO-SILANOLS AND -SILOXANES
Eaborn, Colin,Safa, Kazem D.
, p. 7 - 14 (2007/10/02)
Reaction of the iodides TsiSiMe2I and TsiSiPh2I, (Tsi=(Me3Si)3C) with AgClO4 in t-BuOH provides a route to the silanols TsiSiMe2OH and (Me3Si)2C(SiPh2Me)(SiMe2OH), respectively.TsiSiMe2OH gives the disiloxane TsiSiMe2OSiMe3 when treated with either (a) Me
