83632-54-6

Basic information

• Product Name: nitridomanganese(V) meso-tetraphenylporphyrinate
• Synonyms: nitridomanganese(V) meso-tetraphenylporphyrinate
• CAS NO: 83632-54-6
• Molecular Weight: 681.678
• Mol File: 83632-54-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: nitridomanganese(V) meso-tetraphenylporphyrinate(CAS DataBase Reference)
• NIST Chemistry Reference: nitridomanganese(V) meso-tetraphenylporphyrinate(83632-54-6)
• EPA Substance Registry System: nitridomanganese(V) meso-tetraphenylporphyrinate(83632-54-6)

Safety Data

• Hazardous Substances Data: 83632-54-6(Hazardous Substances Data)

Upstream product

• 34557-72-7 (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride 
• 7664-41-7 ammonia 
• 56413-47-9 azidomanganese(III) meso-tetraphenylporphyrin 
• 55290-32-9 bromo(5,10,15,20-tetraphenylporphyrinato)manganese(III) 
• 58356-65-3 manganese(III) meso-tetraphenylporphyrin acetate 

Downstream Products

• 34557-72-7 (5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride 
• 58356-65-3 manganese(III) meso-tetraphenylporphyrin acetate 
• 28110-70-5 chloro(5,10,15,20-tetraphenylporphyrinato)chromium(III) 
• 84206-82-6 nitridomanganese(V) octaethylporphyrinate 
• 31004-82-7 manganese(II) 5,10,15,20-tetraphenylporphyrinate 

Relevant articles and documents

Pyrolysis of Azidomanganese(III) Porphyrin Affording Nitridomanganese(V) Porphyrin

Azidomanganese(III) meso-tetraphenylporphyrin, MnIII(tpp)N3, in the solid state was pyrolyzed around 236 deg C to yield nitridomanganese(V) meso-tetraphenylporphyrin, MnV(tpp)N.

The patterns of nitrogen atom transfer between manganese(V) and manganese(III) complexes with porphyrins and tetraazaporphyrins

The kinetics of intermetallic nitride nitrogen atom transfer between manganese(V) and manganese(III) complexes with tetraphenylporphin and octaphenyltetraazaporphin were studied. The interaction between the nitridomanganese(V)tetraphenylporphyrin and Mn(I

Photoirradiated and γ-ray-irradiated reactions of manganese(III, IV, V) tetraphenylporphyrins in 2-methyltetrahydrofuran. Reactions of azidomanganese(III) porphyrin

Manganese(III, IV) tetraphenylporphyrins MnIII(TPP)X (TPP = 5,10,15,20-tetraphenylporphinato; X = I, Br, Cl, N3, NCS, OAc) and MnIV(TPP)(OCH3)2 in 2-methyltetrahydrofuran (MeTHF) at room temperature were reduced to yield MnII(TPP) by photoirradiation with visible light (440-750 nm) or by γ-ray irradiation. The photoirradiation of MnIII(TPP)N3 in the rigid matrix at 77 K affords MnV(TPP)N. Photochemically stable MnV(TPP)N was reduced to MnII(TPP) by γ-irradiation at room temperature. γ-Irradiation of MeTHF solutions of MnIII(TPP)X at 77 K causes one-electron reduction to form the constrained complexes [MnII(TPP)X]-. Warming the matrices after γ-irradiation formed MnII(TPP), liberating ligand X-. The near-infrared bands of MnIII(TPP)X red shift along with the shifts of the bands in the visible region by varying the ligand X. The characteristic bands of the constrained complex [MnII(TPP)X]- in the near-infrared region red shift in the order X = Cl > Br > I. The photoirradiation of CrIII(TPP)N3 with visible light affords CrV(TPP)N at room temperature and at 77 K.