83646-56-4Relevant academic research and scientific papers
Fermentation of Fragrances: Biotransformation of β-Ionone by Lasiodiplodia theobromae
Krasnobajew, Victor,Helmlinger, Daniel
, p. 1590 - 1601 (1982)
Pre-grown mycelia of Lasiodiplodia theobromae ATCC 28570 transform β-ionone (1) into a large variety of metabolites, by mainly degrading the side-chain of the β-ionone molecule by a C2-unity.The enzyme system responsible for this degradation is proposed to be an oxygenase, which gives rise to the formation of the main product β-cyclo-homogeraniol (8) in analogy to a Baeyer-Villiger oxidation.Further enzymic actions of Lasiodiplodia such as hydrogenations and hydroxylations lead to an accumulation of several not yet described β-ionone metabolites.
