Helvetica Chimica Acta p. 1590 - 1601 (1982)
Update date:2022-08-05
Topics:
Krasnobajew, Victor
Helmlinger, Daniel
Pre-grown mycelia of Lasiodiplodia theobromae ATCC 28570 transform β-ionone (1) into a large variety of metabolites, by mainly degrading the side-chain of the β-ionone molecule by a C2-unity.The enzyme system responsible for this degradation is proposed to be an oxygenase, which gives rise to the formation of the main product β-cyclo-homogeraniol (8) in analogy to a Baeyer-Villiger oxidation.Further enzymic actions of Lasiodiplodia such as hydrogenations and hydroxylations lead to an accumulation of several not yet described β-ionone metabolites.
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Doi:10.1021/ja00341a038
(1983)Doi:10.1248/cpb.30.3435
(1982)Doi:10.1039/C8NJ03173H
(2018)Doi:10.1021/jo00150a003
(1983)Doi:10.1246/cl.1982.1513
(1982)Doi:10.1021/ic049056a
(2005)
