83659-70-5

Upstream product

• 18424-76-5 dimethyl malonate sodium salt 
• 83659-67-0 1-Nitro-1-vinyl-cyclohexane 
• 108-59-8 malonic acid dimethyl ester 
• 927832-53-9 C₁₃H₂₂O₃ 
• 1122-60-7 1-nitrocyclohexane 

Downstream Products

• 332426-11-6 dimethyl 2-allyl-2-(1-vinylcyclohexyl)malonate 

Relevant academic research and scientific papers

Regioselective rhodium-catalyzed allylic alkylation with a modified Wilkinson's catalyst

Treatment of the secondary and tertiary allylic carbonates 1 with the sodium salt of dimethyl malonate and a catalytic amount of Wilkinson's catalyst modified with a triorganophosphite, furnished the tertiary and quaternary carbon stereogenic centers 2 in

Iron-catalyzed allylic alkylation

A method for performing an iron-catalyzed allylic alkylation includes the preparation of a reaction mixture obtainable from (i) an allylic substrate with the structural element C═C—C—X, wherein X comprises a leaving group that represents a carbonate, (ii) an active Fe(-II) catalyst complex, (iii) at least one ligand, (iv) at least one solvent, and (v) a nucleophile or pronucleophile.

Palladium-catalysed Allylic Alkylations of Allylic Nitro-compounds

In the presence of catalytic amounts of tetrakis(triphenylphosphine)palladium, allylic nitro-compounds undergo allylic alkylations with sodium dimethyl malonate.