836596-29-3Relevant academic research and scientific papers
Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates
Bratt, Emma,Suárez-Pantiga, Samuel,Johansson, Magnus J.,Mendoza, Abraham
, p. 8844 - 8847 (2019)
The oxidative rearrangement of 1,3-diketones is an underexplored alternative to enolate chemistry in the synthesis of all-carbon quaternary carboxylates. The mechanistic investigation of this reaction has resulted in a mild base mediated protocol, whose r
Synthesis of spiro[5.4]decenones and their transformation into bicyclo[4.4]deca-1,4-dien-3-ones by domino "elimination-double-Wagner- Meerwein-rearrangement" reactions
Bose, Gopal,Ullah, Ehsan,Langer, Peter
, p. 6015 - 6028 (2007/10/03)
The [3+3] cyclization of 1,3-bis-silyl enol ethers with 1,1-diacylcyclopentanes allows a convenient synthesis of spiro[5.4]decenones. Treatment of these compounds with trifluoroacetic acid (TFA) afforded a great variety of bicyclo[4.4.0]deca-1,4-dien-3-on
