83731-73-1Relevant academic research and scientific papers
Dinuclear Pd(i) complexes - Solely precatalysts? Demonstration of direct reactivity of a Pd(i) dimer with an aryl iodide
Bonney, Karl J.,Proutiere, Fabien,Schoenebeck, Franziska
, p. 4434 - 4439 (2013)
This report provides experimental, computational and spectroscopic data in support of the direct reactivity of a Pd(i) dimer with an aryl iodide, resulting in Br/I halogen exchange between the complex and the aryl iodide. The reactivity could not be achieved through analogous Pd(0) conditions, demonstrating the distinct reactivities at such multiple Pd-sites. Computational studies support that the direct oxidative addition to ArI by the dinuclear metal complex is energetically feasible.
