83739-25-7Relevant academic research and scientific papers
APPLICATIONS OF THE TANDEM -WITTIG-OXY-COPE REARRANGEMENT TO SYNTHESIS OF exo-BREVICOMIN AND OXOCRINOL. THE SCOPE AND LIMITATION OF THE SIGMATROPIC SEQUENCES AS A SYNTHETIC METHOD FOR δ,ε-UNSATURATED KETONES
Mikami, Koichi,Nakai, Takeshi
, p. 1349 - 1352 (1982)
The synthetic utility of the title sigmatropic sequence is illustrated in the syntheses of (E)-6-nonen-2-one, a precursor of exo-brevicomin, and oxocrinol.The scope and limitation of this sequence as a synthetic method for δ,ε-unsaturated ketones are also discussed.
