Chemistry Letters p. 1349 - 1352 (1982)
Update date:2022-09-26
Topics:
Mikami, Koichi
Nakai, Takeshi
The synthetic utility of the title sigmatropic sequence is illustrated in the syntheses of (E)-6-nonen-2-one, a precursor of exo-brevicomin, and oxocrinol.The scope and limitation of this sequence as a synthetic method for δ,ε-unsaturated ketones are also discussed.
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