83760-06-9Relevant academic research and scientific papers
2-Diazo-1,3-dimesityl-2H-indene and 1,3-Dimesitylisoindenylidene
Jones, David W.,Pomfret, Alan
, p. 249 - 253 (2007/10/02)
Reduction of 1,3-dihydroxy-1,3-dimesitylindan-2-one oxime 5 with HI-HOAc gives the primary enamine, 2-amino-1,3-dimesitylindene 7.This resists hydrolysis to 1,3-dimesitylindan-2-one 6 even with boiling concentrated HCl-dioxane (1:1); steric protection of
Preparation, Thermolysis, and Photolysis of 2-Diazo-1,3-dimesityl-2H-indene: a Sterically Stabilised 2-Diazoindene
Jones, David W.,Pomfret, Alan
, p. 919 - 921 (2007/10/02)
2-Diazo-1,3-dimesityl-2H-indene (2) is prepared by reaction of 2-amino-1,3-dimesityl-2H-indene with sodium nitrite-acetic acid; though isolable (2) decomposes either thermically (20 deg C) or on exposure to visible light to give the hydrocarbons (6), (7),
