83802-85-1Relevant academic research and scientific papers
Radical alkylation of bis(silyloxy)enamine derivatives of organic nitro compounds
Jin, Young Lee,Hong, Young-Taek,Kim, Sunggak
, p. 6182 - 6186 (2007/10/03)
(Chemical Equation Presented) Alkylation β to a nitro group by radical chemistry is made possible by initial conversion of the organic nitro compound into a bis(silyloxy)enamine (see scheme; TBSOTf=tert-butyldimethylsilyl trifluoromethanesulfonate). An advantage of the method is the simultaneous conversion of the nitro group into a synthetically useful oxime ether group.
Stereochemistry of Addition of Organocopper Reagents and of the Hydride Ion to 1-(Arylsulfonyl)bicyclobutanes
Gaoni, Yehiel,Tomazic, Alenka,Potgieter, Eleonora
, p. 2943 - 2947 (2007/10/02)
Addition of methylmagnesium iodide/cuprous iodide or of lithium dimethylcuprate to 2-exo- and 2-endo-methyl-1-(phenylsulfonyl)bicyclobutane and determination of the relative geometry of the methyls in the 2,3-dimethylcyclobutanes obtained allowed u
