83807-56-1Relevant academic research and scientific papers
Synthetic and Biosynthetic Studies of Porphyrins.Part 11.The Synthesis of meso Oxygenated Protoporphyrins.
Jackson, Anthony H.,Rao, K. R. Nagaraja,Wilkins,Martyn
, p. 307 - 312 (2007/10/02)
Treatment of protoporphyrin IX dimethyl ester (12) with benzoyl peroxideaffords a mixyure of the four isomeric meso-benzoiloxy derivaties (13) These have been separated by h.p.l.c. and distinguished from each other by hydrolysis to the corresponding oxophlorins (oxyporphyrins),insertionof iron to form the oxyhaems (3),and oxidation by molecular oxygen to the corresponding biliverdins (7).
Synthesis of the Four meso-Oxyprotoporphyrin Isomers
Jackson, Anthony H.,Rao, K. R. Nagaraja,Wilkins, Martyn
, p. 794 - 796 (2007/10/02)
The four isomers of meso-oxyprotoporphyrin dimethyl esters have been prepared via direct oxidation of protoporphyrin IX dimethyl ester, separated by h.p.l.c., and identified by conversion into the corresponding biliverdins.
