83818-64-8Relevant academic research and scientific papers
Stereoselective Horner-Wittig synthesis of (Z)-1-chlorovinyl sulfoxides
Otten, Pieter A.,Davies, Honorine M.,Van Steenis, Jan Hein,Gorter, Syb,Van Der Gen, Arne
, p. 10527 - 10544 (2007/10/03)
This paper describes the synthesis of (Z)-1-chlorovinyl sulfoxides 1 by the Horner-Wittig reaction. The required [(α-chloro)sulfinylmethyl]diphenylphosphine oxides 2 (R1=Me, c-Hex, Ph, p-Tol, p-(CF3)Ph), were prepared in high yields
Synthesis of Carboxylic Acids and their Methyl Esters from Alkyl Phenyl Sulfides
Fortes, Carlos C.,Fortes, Helena C.,Goncalves, Dioneia C. R. G.
, p. 857 - 858 (2007/10/02)
Alkl phenyl sulfides are converted with sulphuryl chloride and pyridine under controlled temperatures into 1,1-dichloroalkyl phenyl sulfides or 1-chloro-1-enyl sulfides; treatment of these intermediates with methanol-water (1percent v/v) and mercury(II) acetate-formic acid gives, respectively, methyl carboxylic ester and carboxylic acids.
