86895-65-0Relevant academic research and scientific papers
SOLVOLYSIS OF 1-CHLORO-1-ALKENYL PHENYL SULFIDES. SYNTHESIS OF α-BROMO PHENYL THIOCARBOXYLIC ESTERS, α-BROMO ALKYL CARBOXYLIC ESTERS AND α-PHENYLTHIO METHYL CARBOXYLIC ESTERS
Fortes, C. C.,Chaves, M. H.
, p. 751 - 762 (2007/10/02)
1-Chloro-1-alkenyl phenyl sulfides treated with bromine followed by hydrolysis or methanolysis give α-bromo phenyl thiocarboxylic esters and α-phenylthio methyl carboxylic esters.Direct oxidative solvolysis with bromine and alcohol give α-bromo alkyl carboxylic esters.
Synthesis of α-Phenylthio Enones and Esters of α-Phenylthio Alkenoic Acids
Durman, John,Grayson, J.Ian,Hunt, Paul G.,Warren, Stuart
, p. 1939 - 1946 (2007/10/02)
The title compounds can be made by a Pummerer dehydration from the corresponding saturated sulphoxides.The alkylation of anions from saturated and unsaturated ketones is described.
ACYLATION OF EXTENDED ENOLATE IONS FROM α-PHENYLTHIO(PhS-)CROTONATE ESTERS
Durman, John,Warren, Stuart
, p. 2895 - 2898 (2007/10/02)
C-Acylation, like alkylation, occurs at the α-position of title compounds to give unsaturated keto-esters from which the PhS group may be removed.
ALKYLATION OF EXTENDED ENOLATES FROM α-PHENYLTHIO CROTONATE ESTERS
Durman, John,Hunt, Paul G.,Warren, Stuart
, p. 2113 - 2116 (2007/10/02)
Conditions are described for the formation of enolate anions from substituted α-phenylthio-crotonate esters and their alkylation at the α-carbon atom.
