83818-66-0Relevant academic research and scientific papers
Synthesis of Carboxylic Acids and their Methyl Esters from Alkyl Phenyl Sulfides
Fortes, Carlos C.,Fortes, Helena C.,Goncalves, Dioneia C. R. G.
, p. 857 - 858 (1982)
Alkl phenyl sulfides are converted with sulphuryl chloride and pyridine under controlled temperatures into 1,1-dichloroalkyl phenyl sulfides or 1-chloro-1-enyl sulfides; treatment of these intermediates with methanol-water (1percent v/v) and mercury(II) acetate-formic acid gives, respectively, methyl carboxylic ester and carboxylic acids.
A convenient synthesis of phenyl 1-chloro-1 alkenyl chalcogenides by one-pot Wittig reaction. Synthesis of selenolesters
Silveira, Claudio C.,Boeck, Paula,Begnini, Mauro L.,Braga, Antonio L.
, p. 173 - 179 (2007/10/03)
The preparation of 1-chloro-1-chalcogeno(sulfur, selenium) alkenes by a Wittig-type reaction in an one pot procedure is described. Chlorochalcogenyl triphenylphosphoranes are formed in situ by the reaction of dichloromethyl phenylchalcogenide, potassium t
