83932-89-2Relevant academic research and scientific papers
Microwave-assisted cross-metathesis of unsaturated thiocyanates: Application to the synthesis of thiocyanatins A and B and analogues
Cros, Fanny,Pelotier, Beatrice,Piva, Olivier
experimental part, p. 233 - 238 (2010/03/05)
The syntheses of thiocyanatin B and related dithiocyanates have been carried out by cross metathesis of unsaturated thiocyanates promoted by a ruthenium catalyst. The efficiency of the reaction depends strongly on the nature of the catalyst, the length of
The isolation and synthesis of novel nematocidal dithiocyanates from an Australian marine sponge, Oceanapia sp.
Capon,Skene,Liu,Lacey,Gill,Heiland,Friedel
, p. 7765 - 7769 (2007/10/03)
Bioassay-directed fractionation of the EtOH extract of an Oceanapia sp. collected off the northern Rottnest Shelf, Australia, has yielded three novel dithiocyanates, thiocyanatins A (1), B (2a), and C (2b). The structures were determined by detailed spectroscopic analysis and confirmed by total synthesis. In addition to featuring an unprecedented dithiocyanate functionality, thiocyanatins possess an unusual 1,16-difunctionalized n-hexadecane carbon skeleton and are revealed as a hitherto unknown class of nematocidal agent.
HIGH-YIELD CATALYTIC METATHESIS OF ALKENYL TOSYLATES WITH APPLICATIONS IN ORGANIC SYNTHESIS
Daly, Daniel G.,McKervey, M. Anthony
, p. 2997 - 2998 (2007/10/02)
Alkenyl tosylates of the type RCH=CH(CH2)nOTs undergo metathesis using a WCl6-Me3SnCl catalyst system, producing difunctionalised alkenes of the type TsO(CH2)nCH=CH(CH2)nOTs (n=7,8, and 9); examples of the use of
