83948-48-5

Basic information

• Product Name: rel-(3R,4S)-4-Phenyl-3-thiophenoxy-2-azetidinone
• CAS NO: 83948-48-5
• Molecular Weight: 255.34
• Mol File: 83948-48-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: rel-(3R,4S)-4-Phenyl-3-thiophenoxy-2-azetidinone(CAS DataBase Reference)
• NIST Chemistry Reference: rel-(3R,4S)-4-Phenyl-3-thiophenoxy-2-azetidinone(83948-48-5)
• EPA Substance Registry System: rel-(3R,4S)-4-Phenyl-3-thiophenoxy-2-azetidinone(83948-48-5)

Safety Data

• Hazardous Substances Data: 83948-48-5(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 17599-61-0 N-benzylidene-1,1,1-trimethylsilanamine 
• 7605-25-6 ethyl phenylsulfenylacetate 

Relevant articles and documents

N-Trimethylsilyl Imines: Applications to the Synthesis of β-Lactams

Ester enolates and N-trimethylsilyl imines react to afford N-protio-β-lactams.The stereochemical course of the reaction depends on the ester enolate geometry.Therefore (E)-enolates give mainly cis β-lactams while (Z)-enolates give nearly equal mixtures of cis and trans β-lactams.The use of ethyl β-hydroxybutyrate as the ester component allows the preparation of β-lactams of potential use in carbapenem synthesis.The differences in the behavior of N-trimethylsilyl and N-aryl imines in ester-imine condensations are also discussed.