83991-17-7Relevant academic research and scientific papers
UNTERSUCHUNGEN ZUM ELEKTRONISCHEN EINFLUSS VON ORGANYLLIGANDEN.IV. 13-NMR-SPEKTROSKOPISCHE UNTERSUCHUNG DER GEGENSEITIGEN BEEINFLUSSUNG VON ORGANYLLIGANDEN IN TRIETHYLZINNORGANYLVERBINDUNGEN
Steinborn, Dirk,Buthge, Michael,Taube, Rudolf,Radeglia, Reiner,Schlothauer, Klaus,Nowak, Karin
, p. 277 - 286 (1982)
By means of 13C NMR spectroscopy, the coupling constants 1J(119Sn-13CEt) of 18 compounds of the SnEt3R type (R = organo group) have been measured.These coupling constants have been shown to reflect the change induced by R in the s-content of the tin hybrid orbitals of the Sn-CEt bonds.The series of the influence of R obtained on the basis of the coupling constant mentioned as a parameter is compared with a trans-influence series of R obtained on organomercury compounds.Occurring differences are attributed to different modes of bonding of the group R at the central atom.
