83997-43-7Relevant academic research and scientific papers
Facile Formation of trans-Cyclohexanediols by the Aerobic Oxidation of Cyclohexenes with Sodium Disulfite
Kimbara, Nagashige,Izumi, Shunsuke,Hirata, Toshifumi
, p. 1198 - 1200 (1994)
Disulfite was found to be an excellent oxidizing reagent for a gentle and stereoselective reaction to produce trans-diols via corresponding epoxides from the cyclohexenes, such as 1-p-menthen-8-yl acetate, 1,8-p-menthadiene, and 2-pinene.
THE ENANTIOSELECTIVE BIOTRANSFORMATION OF α-TERPINEOL AND ITS ACETATE WITH THE CULTURED CELLS OF NICOTIANA TABACUM
Suga, Takayuki,Hirata, Toshifumi,Lee, Ym Sook
, p. 1595 - 1598 (2007/10/02)
In the biotransformation of the enantiomers of p-ment-1-en-8-ol (α-terpineol) and 8-acetoxy-p-ment-1-ene (α-terpinyl acetate) with the cultured suspension cells of Nicotina tabacum, it was clarified that the cultured cells effected the hydroxylation at the 6-position of (4R)-(+)-enantiomer in preference to the (4S)-(-)-enantiomer, whereas the cells did the hydrolysis of the acetoxyl group and the hydroxylation of the ethylenic linkage of (4S)-(-)-α-terpinyl acetate in preference to the (4R)-(+)-enantiomer.
