Facile Formation of trans-Cyclohexanediols by the Aerobic Oxidation of Cyclohexenes with Sodium Disulfite

DOI: 10.1246/bcsj.67.1198

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1198 - 1200 (1994)

Update date:2022-08-05

Topics:

Authors:

Kimbara, Nagashige

Izumi, Shunsuke

Hirata, Toshifumi

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Article abstract of DOI:10.1246/bcsj.67.1198

Disulfite was found to be an excellent oxidizing reagent for a gentle and stereoselective reaction to produce trans-diols via corresponding epoxides from the cyclohexenes, such as 1-p-menthen-8-yl acetate, 1,8-p-menthadiene, and 2-pinene.

Full text of DOI:10.1246/bcsj.67.1198

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