84004-90-0Relevant academic research and scientific papers
MIXED (η2:η4)-COORDINATION OF para-SEMIQUINOID TRIENE LIGANDS (1-METHYLENE-4,4-DIALKYL-2,5-CYCLOHEXADIENES) WITH TWO TRANSITION METAL CENTRES IN BI- AND TRI-NUCLEAR RHODIUM(I) COMPLEXES
Nikanorov, V. A.,Rozenberg, V. I.,Bakhmutov, V. I.,Reutov, O. A.,Ginzburg, B. I.,et al.
, p. 351 - 362 (2007/10/02)
The reaction between Rh(acac)(C2H4)2 and 1-methylene-4-methyl-4-R-2,5-cyclohexadienes (RC8H9) leads to binuclear complexes 2(C2H4)(RC8H9), where R = CH3, CHCl2 and n-C4H9, in which triene ligands show a mixed (η2:η4) mode o
