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Relative Rate Constants for the Reactions of CF3OF with Olefins in Solution
Navarrini, W.,Russo, A.,Tortelli, V.
, p. 6441 - 6443 (2007/10/03)
The addition reactions of CF3OF to chloro fluoro olefins have been studied in solution at low temperature (-78, -105 deg C), and their relative rate constants have been determined using the kinetic approach of competition reactions.The reactivity and regio- and stereoselectivity are consistent with a free radical chain-propagating reaction in which the alkenes are attacked by the CF3O* radical generated by homolytic cleavage of the O-F bond in the CF3OF molecule.
