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84043-09-4

5-Benzyloxycarbonylamino-5-desoxy-1,2-O-isopropyliden-α-D-glucofuranuronsaeure(t-butyl)ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 84043-09-4 Structure

  • Basic information

    1. Product Name: 5-Benzyloxycarbonylamino-5-desoxy-1,2-O-isopropyliden-α-D-glucofuranuronsaeure(t-butyl)ester
    2. Synonyms: 5-Benzyloxycarbonylamino-5-desoxy-1,2-O-isopropyliden-α-D-glucofuranuronsaeure(t-butyl)ester
    3. CAS NO:84043-09-4
    4. Molecular Formula:
    5. Molecular Weight: 423.463
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 84043-09-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 5-Benzyloxycarbonylamino-5-desoxy-1,2-O-isopropyliden-α-D-glucofuranuronsaeure(t-butyl)ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: 5-Benzyloxycarbonylamino-5-desoxy-1,2-O-isopropyliden-α-D-glucofuranuronsaeure(t-butyl)ester(84043-09-4)
    11. EPA Substance Registry System: 5-Benzyloxycarbonylamino-5-desoxy-1,2-O-isopropyliden-α-D-glucofuranuronsaeure(t-butyl)ester(84043-09-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 84043-09-4(Hazardous Substances Data)

84043-09-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 84043-09-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,4,0,4 and 3 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 84043-09:
(7*8)+(6*4)+(5*0)+(4*4)+(3*3)+(2*0)+(1*9)=114
114 % 10 = 4
So 84043-09-4 is a valid CAS Registry Number.

84043-09-4Relevant articles and documents

Total Synthesis of Nojirimycin

Vasella,Voeffray

, p. 1134 - 1144 (1982)

Addition of the nitrone 3 (from 8 and 9) to furane, followed by oxidation with OsO4 and then isopropylidenation gave the fully functionalized glycoside 12 (40percent from 8) via the glycal 10 and the hemiacetal 11.Since the glycoside cleavage of 12, leading to 13 after benzyloxycarbonylation proceeded in a mediocre yield, and since the acetolysis of 12 giving 14 (69percent) was not practical, compound 12 was transformed into the hydroxy ester 17 by sequential hydrogenolysis, hydrolysis and benzyloxycarbonylation (69percent overall).The hydroxy ester 17 was lactonized to give 18 (87percent).Reduction of 18 first with LiBH4 (97percent) and then with H2/Pd gave the keycompound 20 which was transformed into nojirimycin (1) and into 1-deoxy-nojirimycin (2) using prior art.The overall yield of 1 was 19.5percent.

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