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[Rh(PPh3)2(CO)(purine)]PF6 is a rhodium-based coordination complex, where a rhodium atom is coordinated to two triphenylphosphine (PPh3) ligands, one carbon monoxide (CO) ligand, and one purine ligand. Purine is a heterocyclic aromatic organic compound that is a fundamental component of nucleic acids, such as DNA and RNA. The PF6 (hexafluorophosphate) anion is present to balance the overall charge of the complex. [Rh(PPh3)2(CO)(purine)]PF6 is of interest in the field of organometallic chemistry and may have potential applications in catalysis, medicinal chemistry, and the study of metal-DNA interactions.

84050-01-1

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84050-01-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 84050-01-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,4,0,5 and 0 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 84050-01:
(7*8)+(6*4)+(5*0)+(4*5)+(3*0)+(2*0)+(1*1)=101
101 % 10 = 1
So 84050-01-1 is a valid CAS Registry Number.

84050-01-1Downstream Products

84050-01-1Relevant academic research and scientific papers

Synthesis and infrared and magnetic resonance studies of organorhodium complexes of guanosine, inosine, 1-methylinosine, purine, adenine, and adenosine

Abbott, David W.,Woods, Clifton

, p. 597 - 602 (2008/10/08)

Solid complexes of the type [Rh(PPh3)2(CO)L]PF6 (L = guanosine, inosine, 1-methylinosine, purine, adenine, adenosine) have been prepared by the reaction of nucleic base derivatives and [Rh(PPh3)2(CO)3]PF6 in a 1:1 ratio in CH2Cl2/CH3OH. The complexes have been characterized by 1H, 13C{1H}, and 31P{1H} NMR spectroscopy and infrared spectroscopy in (CD3)2SO and CH2Cl2. Data that support binding at O6 of guanosine, inosine, and 1-methylinosine are presented. The binding preferences of the electrophile [Rh(PPh3)2(CO)]+ are discussed in terms of possible steric interactions.

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