840524-75-6

Upstream product

• 216320-01-3 5-iodo-2,3-dimethyl-2-pentene 
• 840524-87-0 (R)-2-(3,4-Dimethyl-pent-3-enyl)-2-methoxymethyl-malonic acid methyl ester 2-trimethylsilanyl-ethyl ester 
• 840524-88-1 (R)-2-(3,4-Dimethyl-pent-3-enyl)-2-methoxymethyl-malonic acid mono-(2-trimethylsilanyl-ethyl) ester 
• 840524-71-2 (S)-2-(3,4-dimethyl-3-pentenyl)-2-methoxymethylmalonic acid monomethyl ester 
• 840524-70-1 dimethyl 2-(3,4-dimethyl-3-pentenyl)-2-methoxymethylmalonate 
• 2916-68-9 2-(Trimethylsilyl)ethanol 
• 840524-73-4 (S)-2-fluorocarbonyl-2-methoxymethyl-5,6-dimethylhept-5-enoic acid 2-trimethylsilylethyl ester 

Downstream Products

• 840524-76-7 (R)-4-bromo-3-[3-methoxymethyl-6,7-dimethyl-2-oxo-3-(2-trimethylsilylethoxycarbonyl)oct-6-enyl]benzoic acid methyl ester 
• 840524-79-0 3-[(2R,3R)-2-acetoxy-3-formylamino-3-methoxymethyl-6,7-dimethyloct-6-enyl]-4-bromobenzoic acid methyl ester 
• 840524-77-8 4-bromo-3-[(2R,3R)-2-hydroxy-3-methoxymethyl-6,7-dimethyl-3-(2-trimethylsilylethoxycarbonyl)oct-6-enyl]benzoic acid methyl ester 
• 840524-78-9 4-bromo-3-[(2S,3R)-2-hydroxy-3-methoxymethyl-6,7-dimethyl-3-(2-trimethylsilylethoxycarbonyl)oct-6-enyl]benzoic acid methyl ester 

Relevant academic research and scientific papers

A stereodivergent synthesis of virantmycin by an enzyme-mediated diester desymmetrization and a highly hindered aryl amination

(Chemical equation presented). Both enantiomers of the antiviral agent virantmycin were synthesized in a sequence of reactions in which the key steps were a highly stereoselective porcine liver esterase(PLE) mediated desymmetrization of a prochiral dieste