840529-73-9Relevant academic research and scientific papers
Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines
Okamoto, Kazuhiro,Hayashi, Tamio,Rawal, Viresh H.
supporting information; experimental part, p. 4815 - 4817 (2009/12/08)
Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.
C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines
Otomaru, Yusuke,Tokunaga, Norihito,Shintani, Ryo,Hayashi, Tamio
, p. 307 - 310 (2007/10/03)
(Chemical Equation Presented) Asymmetric synthesis of diarylmethylamines with high enantioselectivity (95-99percent ee) was realized by use of a new C 2-symmetric diene ligand, (1R,5R)-2,6-diphenylbicyclo[3.3.1]nona-2,6- diene (Ph-bnd*), for th
