84099-50-3

Basic information

• Product Name: 4-(2-propenyl)cyclohexene-1-yl(1-methoxycycloprop-1-yl)methanol
• Synonyms: 4-(2-propenyl)cyclohexene-1-yl(1-methoxycycloprop-1-yl)methanol
• CAS NO: 84099-50-3
• Molecular Weight: 222.327
• Mol File: 84099-50-3.mol

Chemical Properties

• CAS DataBase Reference: 4-(2-propenyl)cyclohexene-1-yl(1-methoxycycloprop-1-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(2-propenyl)cyclohexene-1-yl(1-methoxycycloprop-1-yl)methanol(84099-50-3)
• EPA Substance Registry System: 4-(2-propenyl)cyclohexene-1-yl(1-methoxycycloprop-1-yl)methanol(84099-50-3)

Safety Data

• Hazardous Substances Data: 84099-50-3(Hazardous Substances Data)

Upstream product

• 2111-75-3 perillaldehyde 
• 75697-56-2 1-methoxy-1-(phenylthio)cyclopropane 
• 18031-40-8 (S)-(-)-perillaldehyde 
• 75697-62-0 α-lithiocyclopropyl methyl ether 

Downstream Products

• 79402-29-2 2-<4-(2-propenyl)cyclohexen-1-yl>cyclobutanone 
• 79402-29-2 2-(4-Isopropenyl-cyclohex-1-enyl)-cyclobutanone 

Relevant articles and documents

EFFICIENT SYNTHESYS OF 2-VINYLCYCLOBUTANONES BY THE REARRANGEMENT OF 1-METHOXY-1-CYCLOPROPYLCARBINOLS UNDER NEUTRAL CONDITIONS

A common synthesis of cyclobutanones involves the rearrangement of 1-alkoxy- or 1-(phenylthio)cyclopropylcarbinols under acidic conditions.We report that the synthetically useful 2-vinylcyclobutanones can be prepared in good yield in the absence of proton

PRACTICAL METHOD FOR USING ALKOXIDE-ACCELERATED VINYLCYCLOBUTANE RING EXPANSIONS IN THE SYNTHESIS OF SIX-MEMBERED RINGS. UNEXPECTED ORBITAL SYMMETRY ALLOWED AND FORBIDDEN 1,3-SIGMATROPIC REARRANGEMENTS.

A practical method for utilizing the ring expansion of 2-vinylcyclobutanols to cyclohex-3-en-1-ols, even in cases in which very acid-sensitive groups are present, consists of the addition of 1-lithio- 1-methoxycyclopropanes to conjucated enals, brief trea

A SYNTHESIS OF 2-VINYLCYCLOBUTANONES USING 1-METHOXYCYCLOPROYLLITHIUM REAGENTS

A facile synthesis of 2-vinylcyclobutanones consists of reductive lithiation of 1-phenylthio-1-methoxycyclopropanes, addition of enals or enones to the resulting α-lithioethers, and acid catalyzed rearrangement of the allylic alcohols thus produced.