84101-38-2Relevant academic research and scientific papers
UNSYMMETRICAL DITELLURIDES AS LIGANDS: REACTIONS WITH COPPER(I) AND MERCURY(II) HALIDES
Al-Rubaie, Ali Z.,McWhinnie, William R.
, p. 59 - 64 (1982)
Reactions between copper(I) halides or mercury(II) halides and equimolar mixtures of diphenylditelluride (R2Te2) and bis(p-ethoxyphenylditelluride (R'2Te2) give materials of stoichiometry (M=Cu, X=Cl, Br, n=1; M=Hg, X=Cl, Br, n=2).Change of solvent from propionitrile to ethanol gives m.Mass spectroscopic data and Raman spectra are presented and discussed in terms of the probability that the unsymmetrical ditelluride is present as a ligand. ν(TeTe) for PhTeTe(C6H4OEt-p) occurs at 170.5 cm-1 in benzene solution.
