84104-07-4Relevant articles and documents
A NEW SYNTHETIC METHOD OF α,Β-UNSATURATED KETONES VIA REGIOSELECTIVE REACTION OF ALLYL ANION FORMED FROM 2-MORPHOLINO-3-BUTENENITRILES (MASKED ACYL ANION EQUIVALENTS) WITH ALKYL HALIDES FOLLOWED BY HYDROLYSIS
Takahashi, Kazumasa,Honma, Akira,Ogura, Katsuyuki,Iida, Hirotada
, p. 1263 - 1266 (1982)
Treatment of 2-morpholino-3-butenenitriles and alkyl halides regioselectively afforded products alkylated on α-position to the nitrile group.The hydrolysis of the α-alkylation products gave the α,β-unsaturated ketones in good yields.