A NEW SYNTHETIC METHOD OF α,Β-UNSATURATED KETONES VIA REGIOSELECTIVE REACTION OF ALLYL ANION FORMED FROM 2-MORPHOLINO-3-BUTENENITRILES (MASKED ACYL ANION EQUIVALENTS) WITH ALKYL HALIDES FOLLOWED BY HYDROLYSIS

DOI: 10.1246/cl.1982.1263

Source and publish data:

Chemistry Letters p. 1263 - 1266 (1982)

Update date:2022-08-05

Topics:

Authors:

Takahashi, Kazumasa

Honma, Akira

Ogura, Katsuyuki

Iida, Hirotada

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Article abstract of DOI:10.1246/cl.1982.1263

Treatment of 2-morpholino-3-butenenitriles and alkyl halides regioselectively afforded products alkylated on α-position to the nitrile group.The hydrolysis of the α-alkylation products gave the α,β-unsaturated ketones in good yields.

Full text of DOI:10.1246/cl.1982.1263

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