A NEW SYNTHETIC METHOD OF α,Β-UNSATURATED KETONES VIA REGIOSELECTIVE REACTION OF ALLYL ANION FORMED FROM 2-MORPHOLINO-3-BUTENENITRILES (MASKED ACYL ANION EQUIVALENTS) WITH ALKYL HALIDES FOLLOWED BY HYDROLYSIS

DOI: 10.1246/cl.1982.1263

Source and publish data:

Chemistry Letters p. 1263 - 1266 (1982)

Update date:2022-08-05

Topics:

Authors:

Takahashi, Kazumasa

Honma, Akira

Ogura, Katsuyuki

Iida, Hirotada

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1982.1263

Treatment of 2-morpholino-3-butenenitriles and alkyl halides regioselectively afforded products alkylated on α-position to the nitrile group.The hydrolysis of the α-alkylation products gave the α,β-unsaturated ketones in good yields.

Full text of DOI:10.1246/cl.1982.1263

Products guided by the article

Product name:2-morpholino-4-phenyl-2-hexenenitrile

Cas No:84104-07-4

R&D Labs maybe for 84104-07-4

MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Forsman Scientific(Beijing)co.,Ltd.

Contact:+86-10-64646565

Address:Rm No.1301, Building-2, No. A-13 Beiyuan Road, Chaoyang District Beijing, China, PR,
Chongqing maohuan Chemicals Co., Ltd

website:http://www.bschem.com

Contact:+86 13996103726

Address:Chongqing Nan'an District Tu Town
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.

Relevant to this article

Syntheses in enantiopure form of four diastereoisomeric naphthopyranquinones derived from aphid insect pigments

Doi:10.1039/b414213f
(2005)
UEBERGANGSMETALL-SUBSTITUIERTE PHOSPHANE, ARSENE UND STIBANE. XLII. KOHLENMONOXID/ISONITRIL-AUSTAUSCH AN DEN METALLO-ARSANEN Cp(OC)3W-AsR2 (R = Me, t-Bu)

Doi:10.1016/0022-328X(84)80136-9
(1984)
Novel base-induced rearrangements of α- and N-halo derivatives of S-ary-S-[(1,2-benzisoxazol-3-yl)methyl]sulfoximides to the corresponding N-sulfinylimines

Doi:10.1248/cpb.30.2820
(1982)
CHROMIUM(II) MEDIATED THREO SELECTIVE SYNTHESIS OF HOMOALLYL ALCOHOLS

Doi:10.1016/S0040-4039(01)82859-8
(1981)
PERISELECTIVE CYCLOADDITION REACTION OF 3-PHENYLTHIA^IV ZOLO<4,3-a>ISOINDOLE TO ELECTRON-DEFICIENT OLEFIN

Doi:10.1246/cl.1982.1533
(1982)
A new approach to the 1,4-benzodiazepine ring system

Doi:10.1055/s-1982-29948
(1982)

Article Doi