84107-47-1Relevant articles and documents
Photoinduced electron transfer reactions of aryl olefins. 2. Cis-trans isomerization and cycloadduct formation in anethole-fumaronitrile systems in polar solvents
Goez, Martin,Eckert, Gerd
, p. 140 - 154 (1996)
In acetonitrile, the photoreactions of cis-anethole, cA, or trans-anethole, tA, with fumarodinitrile, FN, lead to isomerization of both substrate and quencher and to mixed [2 + 2] cycloaddition. By NMR analysis and by NOE measurements it was shown that th
Benign catalysis with iron: Facile assembly of cyclobutanes and cyclohexenes: Via intermolecular radical cation cycloadditions
Yu, Yushuang,Fu, Yu,Zhong, Fangrui
supporting information, p. 1743 - 1747 (2018/04/30)
We describe novel and facile iron-catalyzed crossed intermolecular radical cation cycloadditions of styrenes. This catalysis features high efficiency, atom economy, stereospecificity, scalability and very mild reaction conditions. Thus, these reactions re
Electronically Mismatched Cycloaddition Reactions via First-Row Transition Metal, Iron(III)-Polypyridyl Complex
Shin, Jung Ha,Seong, Eun Young,Mun, Hyeon Jin,Jang, Yu Jeong,Kang, Eun Joo
supporting information, p. 5872 - 5876 (2018/09/25)
The iron(III)-polypyridyl complex and its derivatives showed sufficient oxidizing potential to act as a one-electron oxidant, producing radical cations from olefins and promoting the efficient radical cation [2 + 2] and [2 + 4] cycloaddition reactions. Subsequent chain propagation afforded trisubstituted cyclobutane or cyclohexene derivatives, and this facile route enables the replacement of rare metals with sustainable, green, and inexpensive iron in radical cation cycloadditions.