84110-23-6Relevant academic research and scientific papers
Allyl 1,1-bimetallic species: Their preparation and reactivity profile
Lautens, Mark,Ben, Robert N.,Delanghe, Patrick H.M.
, p. 7221 - 7234 (1996)
A synthesis of novel allyl 1,1-hetero- and homobimetallic compounds where M = Sn or Si' and M' = Si via a palladium catalyzed reduction employing ammonium formate is described. The regioselectivity in the reductions is routinely > 99:1. Reaction of these
The regioselectivity of 1,3-disubstituted allylmetal species towards electrophiles: 1-(Trimethylsilyl)alk-2-enylpotassium compounds
Schlosser, Manfred,Franzini, Livia
, p. 707 - 709 (2007/10/03)
1-(Trimethylsilyl)alk-2-enylpotassium species are readily generated by deprotonation of (alk-2-enyl)trimethylsilanes with the superbasic mixture of butyllithium and potassium tert-butoxide. Like the parent compound 1- (trimethylsilyl)allylpotassium, they too react with a variety of electrophiles preferentially, if not exclusively, at the silyl-distant terminus of the allyl moiety, thus producing branched enesilanes. The opposite regioselectivity previously observed with iodomethane hence appears to be an exception.
LE BIS(TRIMETHYLSILYL)-1,3-PROPENE COMME PRECURSEURS DES SILYL-1-BUTADIENES; ETUDE DE LEUR COMPLEXATION PAR Fe(CO)5, Fe2(CO)9, ET (MeCp)Mn(CO)3
Corriu, R.,Escudie, N.,Guerin, C.
, p. 207 - 216 (2007/10/02)
Reactions of 1,3-bis(trimethylsilyl)propene with carbonyl compounds in the presence of fluoride ions as catalysts, produce selectively (E)-1-trimethylsilylbut-1-en-4-ol. 1,3-Bis(trimethylsilyl)propenyllithium reacts with carbonyl compounds, under formatio
