84113-73-5Relevant academic research and scientific papers
TETRAZOLES. XIV. KINETICS AND RATIO OF PRODUCTS IN THE ALKYLATION OF SALTS OF SUBSTITUTED 5-PHENYLTETRAZOLES WITH ETHYL BROMOACETATE IN ACETONITRILE
Poplavskii, V.S.,Titova, I.E.,Ostrovskii, V.A.,Koldobskii, G.I.
, p. 1738 - 1742 (2007/10/02)
The reaction kinetics and the product ratios were studied for the alkylation of the potassium salts of a series of substituted 5-phenyltetrazoles by ethyl bromoacetate in acetonitrile.Comparison of the obtained data with the results from investigation of the reaction of the same salts with dimethyl sulfate made it possible to consider that the alkylation of tetrazolate anions takes place by a two stage mechanism.
