84119-82-4

Upstream product

• 57384-22-2 ClCo(III)TPP(py) 
• 591-51-5 phenyllithium 
• 18620-02-5 (4-bromophenyl)magnesium bromide 
• 60166-11-2 (5,10,15,20-tetraphenylporphyrinato)bromocobalt(III) 
• 60166-10-1 [5,10,15,20-tetraphenylporphyrin]cobalt(III) chloride 
• 108-86-1 bromobenzene 
• 14172-90-8 cobalt(II) 5,10,15,20-tetraphenylporphyrin 

Downstream Products

• 98150-02-8 [(N-phenyl-tetraphenylporphyrinato)chlorocobalt(II)] 
• 52389-25-0 tris(2,2’-bipyridine)ruthenium(II) 

Relevant academic research and scientific papers

Optical properties and electronic structures of axially-ligated group 9 porphyrins

A series of group 9 metal tetra-(p-tolyl)-porphyrin (M(ttp), M = Co(II), Rh(III), Ir(III)) complexes with axial phenyl substituents have been synthesized and characterized. An aryl bromide cleavage reaction of transition metal complexes was used to prepar

Base-promoted aryl-bromine bond cleavage with cobalt(ii) porphyrins via a halogen atom transfer mechanism

Aryl-bromine bonds are successfully cleaved by cobalt(ii) porphyrins in basic media to give Co(por)Ar (por = porphyrin) in good yields. Mechanistic studies suggested that the aryl-bromine bond is cleaved through a halogen atom transfer mechanism, which is different from the aryl-halogen bond cleavage mechanism with other group 9 metalloporphyrins. This journal is the Partner Organisations 2014.

Acid-catalysed Intramolecular Cobalt to Nitrogen Aryl Migration and Intramolecular Reverse Reaction in Cobalt Porphyrins. Synthesis of N-Phenylporphyrins

On acid treatment phenylcobalt(III)porphyrins yielded N-phenylporphyrin bases, while the reverse reaction was performed upon metallation by cobalt(II) and reduction; double labelling experiments showed that both migrations are intramolecular.