841271-80-5Relevant academic research and scientific papers
Stereospecific, enantioselective allylation of α-hydrazono esters by using allyltrichlorosilanes with BINAP dioxides as neutral-coordinate organocatalysts
Ogawa, Chikako,Sugiura, Masaharu,Kobayashi, Shu
, p. 6491 - 6493 (2004)
(Chemical equation presented). Excellent diastereo- and enantioselectivities were obtained in the title reaction, (E)-Crotylsilanes gave syn adducts, whereas anti adducts were obtained from (Z)-crotylsilanes (see scheme).
PROCESS FOR THE ALLYLATION OF N-ACYLHYDRAZONES
-
Page/Page column 7, (2008/06/13)
[PROBLEMS] To provide a novel method for the allylation of N-acylhydrazones by which enantioselectively allylated N-acylhydrazines can be efficiently obtained. [MEANS FOR SOLVING PROBLEMS] A method for the production of enantioselectively allylated N-acyl
