18147-55-2

Upstream product

• 10025-78-2 trichlorosilane 
• 106-99-0 buta-1,3-diene 
• 563-47-3 3-Chloro-2-methylpropene 

Downstream Products

• 13436-83-4 2-Butenyltrimethoxysilane 
• 25201-44-9 (1R,2S)-2-methyl-1-phenylbut-3-en-1-ol 
• 25201-44-9 (1R,2R)-2-methyl-1-phenylbut-3-en-1-ol 
• 81171-82-6 (3-phenylbutyl)trichlorosilane 
• 84118-90-1 (anti)-(E)-3-hydroxy-4-methyl-1-phenyl-1,5-hexadiene 
• 84118-90-1 (syn)-(E)-3-hydroxy-4-methyl-1-phenyl-1,5-hexadiene 
• 83173-74-4 (anti)-4-hydroxy-3-methyl-6-phenyl-1-hexene 
• 104011-57-6 4-methyl-1-phenylhex-5-en-3-ol 
• 52922-10-8 (1SR,2SR)-2-methyl-1-phenylbut-3-en-1-ol 
• 63553-62-8 (1S*,2R*)-2-methyl-1-phenylbut-3-en-1-ol 
• 93965-64-1 1-cyclohexyl-2-methylbut-3-en-1-ol 
• 93965-64-1 (1RS,2RS)-1-cyclohexyl-2-methyl-3-buten-1-ol 
• 25201-44-9 2-methyl-1-phenyl-3-butene-1-ol 

Relevant academic research and scientific papers

Pyrolysis of trichlorosilane in the presence of chloroform

The pyrolysis of trichlorosilane in the presence of different amounts of chloroform and the copyrolysis of HSiCl3 with buta-1,3-diene in the presence of 1 mol.% chloroform were studied. The enthalpies of formation of products resulting from the pyrolysis of HSiCl3 in the presence of chloroform were calculated by the quantum chemical method. Based on the thermochemical data as well as data from GLC and mass spectrometry, it was concluded from the condensate composition that introduction of chloroform into the zone of pyrolysis of HSiCl3 favors generation of silylenes.

Reaction of Hexachlorodisilane with Methallyl Chloride in the Gas Phase. Syntheses of Trichloro(2-niethyl-2-propenyl)silane

Reaction of methallyl chloride with hexachlorodisilane in the gas phase at 520°C was studied. Trichloro(2-methyl-2-propenyl)silane was shown to be the main reaction product. Among side products of the reaction, (cis-2-butenyl)trichlorosilane, heterocyclic, and aromatic organosilicon compounds were found. A mechanism of the reaction between hexachlorodisilane and methallyl chloride is proposed. It was shown that dichlorosilylenes generated from hexachlorodisilane prefer to react with methallyl chloride which has two reaction centers (C-Cl and C=C) at the C-Cl bond.