84159-64-8Relevant articles and documents
Non-oxidative vanadium-catalyzed co bond cleavage: Application to degradation of lignin model compounds
Son, Sunghee,Toste, F. Dean
supporting information; experimental part, p. 3791 - 3794 (2010/08/22)
(Chemical Equation Presented) New direction: Changes In the ligand structure divert the reactivity of vanadium (V) oxo complexes from alcohol oxidation to a novel non-oxidative C-O bond cleavage. Thus, highly functionalized aryl enones can be selectively generated from lignin model compounds by vanadium-catalyzed cleavage of the β-O-4 linkage (see scheme; N blue, O red).