84175-29-1Relevant academic research and scientific papers
Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: The utility of propylene carbonate
Lenden, Philip,Ylioja, Paul M.,Gonzalez-Rodriguez, Carlos,Entwistle, David A.,Willis, Michael C.
supporting information; experimental part, p. 1980 - 1982 (2011/10/03)
Propylene carbonate is an excellent solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions, allowing a variety of β-S-aldehydes and alkynes to be combined in high yields, to deliver enone products. The effective use of propylene carb
Reaction of β-Alkylthiopropionyl Tetrafluoroborates with Alkenes
Nenajdenko, Valentine G.,Lebedev, Mikhail V.,Balenkova, Elizabeth S.
, p. 6317 - 6320 (2007/10/02)
The reaction of β-alkylthiopropionyl tetrafluoroborates with alkenes results in formation of 6-membered cyclic sulfonium salts.Succeeding cleavage of sulfonium salts by bases affords the corresponding 5-alkylthiopent-1-en-3-ones.
