84200-36-2Relevant academic research and scientific papers
PALLADIUM-CATALYZED REACTION OF ALLYLIC AMMONIUM BROMIDES WITH NUCLEOPHILES
Hirao, Toshikazu,Yamada, Naoto,Ohshiro, Yoshiki,Agawa, Toshio
, p. 409 - 414 (1982)
The reactions of allylic triethylammonium bromides and dimethylsulfonium bromide with carbon nucleophiles were catalyzed by tetrakis(triphenylphosphine)palladium to afford olefinic esters and ketones.
Triethylborane as an efficient promoter for palladium-catalyzed allylation of active methylene compounds with allyl alcohols
Kimura, Masanari,Mukai, Ryutaro,Tanigawa, Naoko,Tanaka, Shuji,Tamaru, Yoshinao
, p. 7767 - 7777 (2007/10/03)
Without prior activation of allyl alcohols, allylation of a variety of active methylene compounds with allyl alcohols proceeds smoothly at rt-50°C in the presence of catalytic amounts of Pd(OAc)2 (1-10mol%), Et 3B (30-240mol%), a phosphine ligand (1-20mol%), and a base (0 to 50-60mol%).
