84212-96-4

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 163041-61-0 Trimethyl-(2-methylselanylmethyl-allyl)-silane 
• 115413-92-8 5-methyl-1-phenyl-5-hexen-3-ol 
• 18388-03-9 2-chloromethyl-3-trimethylsilyl-1-propene 
• 164662-96-8 1-trimethylsilyl-2-(tributylstannyl)methyl-2-propene 
• 84212-94-2 (5-Trimethylsilanylmethyl-3-trimethylsilanyloxy-hex-5-enyl)-benzene 
• 98754-04-2 4-hydroxy-6-phenyl-2-(trimethylgermylmethyl)-1-hexene 

Downstream Products

• 77862-52-3 2-(2-Phenylethyl)-4-methylenetetrahydrofuran 
• 365404-47-3 acetic acid 2-chloro-1-(1-phenethyl-3-trimethylsilanylmethyl-but-3-enyloxy)-ethyl ester 
• 365404-22-4 Trimethyl-(2-methylene-6-phenyl-4-vinyloxy-hexyl)-silane 
• 365404-46-2 chloro-acetic acid 1-phenethyl-3-trimethylsilanylmethyl-but-3-enyl ester 

Relevant academic research and scientific papers

Preparation of Bifunctional Allylboron Reagent and Application to Aldehyde Allylboration

Synthesis of a bifunctional allylboron reagent via Ni-catalyzed borylation of allylic acetate is reported. Subsequent allylation of aldehydes gave homoallylic alcohols in good yields. The allylsilane moiety in the alcohol product serves as a useful handle

Pyran annulation: asymmetric synthesis of 2,6-disubstituted-4-methylene tetrahydropyrans.

[reaction: see text] A reaction process for the asymmetric construction of a variety of cis or trans disubstituted pyrans is described. This sequences allows for the asymmetric convergent union of two aldehydes with silyl-stannane reagent 1 in a two-step

Preparation and synthetic utility of 2-methylselenomethyl allyl methyl selenide. A valuable precursor to 2-silylmethylallyllithiums

3-Lithio-2-[silylmethyl]propenes, easily prepared from 3-methylseleno-2-[silylmethyl]propenes by the cleavage of the C-Se bond, are useful intermediates for the preparation of a variety of functionalised allylsilanes. These allylsilanes are interesting bu

Iodine(III)-Mediated Intramolecular Cyclization of Hydroxy Allylsilanes: Synthesis of 5- or 6-Membered β-Methylene Cyclic Ethers

Oxidative cyclization of hydroxy allylsilanes utilizing the combination of a hypervalent organoiodine compound and a Lewis acid was studied.The allylsilanes 4, prepared from the γ-lactones 1 via conversion to the bis(trimethylsilylmethyl)carbinols 3, on t

Hypervalent Organoiodine Chemistry: a New Synthesis of β-Methylene Cyclic Ethers

The allylsilanes (1), containing suitably-substituted hydroxy-groups, on treatment with iodosylbenzene in the presence of BF3-Et2O in an ether solvent, give 5- or 6-membered β-methylene cyclic ethers (3) in good yields, presumably via the highly reactive