842120-12-1Relevant articles and documents
Single-Layered Chiral Nanosheets with Dual Chiral Void Spaces for Highly Efficient Enantiomer Absorption
Feng, Xiaopeng,Kim, Jehan,Lee, Myongsoo,Liu, Xin,Shen, Bowen,Sun, Bo
, p. 11355 - 11359 (2020)
Although considerable effort in recent years has been devoted to the development of two-dimensional nanostructures, single-layered chiral sheet structures with a lateral assembly of discrete clusters remain elusive. Here, we report single-layered chiral 2
A Solid-Solution Approach for Redox Active Metal-Organic Frameworks with Tunable Redox Conductivity
Mohammad-Pour, Gavin S.,Hatfield, Kendrich O.,Fairchild, David C.,Hernandez-Burgos, Kenneth,Rodríguez-López, Joaquín,Uribe-Romo, Fernando J.
supporting information, p. 19978 - 19982 (2019/12/24)
Systematically tuning the conductivity of metal-organic frameworks (MOFs) is key to synergizing their attractive synthetic control and porosity with electrochemical attributes useful in energy and sensing technologies. A priori control of charge transfer
Porous interpenetrated zirconium-organic frameworks (PIZOFs): A chemically versatile family of metal-organic frameworks
Schaate, Andreas,Roy, Pascal,Preusse, Thomas,Lohmeier, Sven Jare,Godt, Adelheid,Behrens, Peter
, p. 9320 - 9325 (2011/10/02)
We present the synthesis and characterization of porous interpenetrated zirconium-organic frameworks (PIZOFs), a new family of metal-organic frameworks obtained from ZrCl4 and the rodlike dicarboxylic acids HO 2C[PE-P(R1,R2)-EP]CO2H that consist of alternating phenylene (P) and ethynylene (E) units. The substituents R 1,R2 were broadly varied (alkyl, Oalkyl, oligo(ethylene glycol)), including postsynthetically addressable substituents (amino, alkyne, furan). The PIZOF structure is highly tolerant towards the variation of R 1 and R2. This together with the modular synthesis of the diacids offers a facile tuning of the chemical environment within the pores. The PIZOF structure was solved from single-crystal X-ray diffraction analysis. The PIZOFs are stable under ambient conditions. PIZOF-2, the PIZOF prepared from HO2C[PE-P(OMe,OMe)-EP]CO2H, served as a prototype to determine thermal stability and porosity. It is stable up to 325°C in air as determined by using thermogravimetry and powder X-ray diffraction. Argon sorption isotherms on PIZOF-2 revealed a Brunauer-Emmett-Teller (BET) surface area of 1250 m2 g-1 and a total pore volume of 0.68 cm3 g-1. Copyright