84262-76-0

Upstream product

• 1197032-79-3 (PCy₃)2(CO)RuCl(C(CHPh)(O₂CC₆H₄-p-OMe)) 
• 65-85-0 benzoic acid 
• 100-09-4 4-methoxybenzoic acid 
• 536-74-3 phenylacetylene 

Relevant academic research and scientific papers

Steric control at the wingtip of a bis-N-heterocyclic carbene ligand: Coordination behavior and catalytic responses of its ruthenium compounds

Changing the N-substituents of a methylene-linked bis-NHC ligand from n-butyl to bulky mesityl shifts ligand coordination from normal/normal to normal/abnormal mode. The mesityl wingtip groups afford [RuII( MesNHC(CH2)NHC

Scope and mechanistic investigations on the solvent-controlled regio- and stereoselective formation of enol esters from the ruthenium-catalyzed coupling reaction of terminal alkynes and carboxylic acids

The ruthenium-hydride complex (PCy3)2(CO)RuHCl was found to be a highly effective catalyst for the alkyne-to-carboxylic acid coupling reaction to give synthetically useful enol ester products. A strong solvent effect was observed for