84280-43-3Relevant articles and documents
One-Step Conversion of Potassium Organotrifluoroborates to Metal Organoborohydrides
Bateman, Christopher M.,Beal, Hailey,Barker, Joshua E.,Thompson, Brena L.,Donovan, Drake,Grant, Bradley J.,Shooter, Jesse,Arakawa, Jordan H.,Johnson, Spencer,Allen, Caleb J.,Yates, James L.,Kato, Ryota,Tinsley, Colby W. K.,Zakharov, Lev. N.,Abbey, Eric R.
, p. 3784 - 3787 (2018)
This letter describes the one-step conversion of heteroatom-substituted potassium organotrifluoroborates (KRBF3) to metal monoorganoborohydrides (MRBH3) using alkali metal aluminum hydrides. The method tolerates a variety of functional groups, expanding MRBH3 diversity. Hydride removal with Me3SiCl in the presence of dimethylaminopyridine (DMAP) affords the organoborane·DMAP (RBH2·DMAP) adducts.