lithium benzyltrihydroborate

Base Information

• Chemical Name: lithium benzyltrihydroborate
• CAS No.: 84280-43-3
• Molecular Formula: C₇H₁₀B*Li
• Molecular Weight: 111.908
• Mol file: 84280-43-3.mol

Synonyms:lithium benzyltrihydroborate

Chemical Property of lithium benzyltrihydroborate

Chemical Property:

Purity/Quality:

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Technology Process of lithium benzyltrihydroborate

There total 5 articles about lithium benzyltrihydroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

lithium aluminium tetrahydride (16853-85-3) + potassium benzyltrifluoroborate → lithium benzyltrihydroborate (84280-43-3)

Guidance literature:

In tetrahydrofuran; at 22 ℃; for 24h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.orglett.8b01373

Reference yield: 80.0%

n-butyllithium (109-72-8) + trimethylamine borane (1231953-83-5) → lithium borohydride + lithium [butyl(trihydrido)borate] (82111-98-6) + lithium [(dimethylamino)methyl]trihydroborate (84280-42-2) + lithium benzyltrihydroborate (84280-43-3)

Guidance literature:

In hexane; toluene; under dry N2, refluxing for 30 min;

Reference yield:

lithium tri-t-butoxyaluminum hydride + potassium benzyltrifluoroborate → lithium benzyltrihydroborate (84280-43-3)

Guidance literature:

In tetrahydrofuran; at 22 ℃; for 24h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.orglett.8b01373

upstream raw materials:

n-butyllithium

trimethylamine borane

isopropyllithium

lithium aluminium tetrahydride