84308-35-0Relevant academic research and scientific papers
ASYMMETRIC CONJUGATE ADDITION OF COPPER AZAENOLATES AS SYNTHETIC EQUIVALENT OF ENOLATES TO CYCLIC ENONES
Yamamoto, Keiji,Iijima, Masayuki,Ogimura, Yoshinobu
, p. 3711 - 3714 (1982)
Asymmetric conjugate addition to prochiral cyclic enones was devised by using copper azaenolates derived from an acetone imine of optically active amino ethers which were prepared from α-amino acids, the optical yields of the resulting 3-acetonylcycloalkanones being found to attain as high as 75percent e.e.
