84322-56-5

Basic information

• Product Name: 1,3,5-Trifluoro-2,4,6-triiodobenzene
• Synonyms: 1,3,5-TRILFLUORO-2,4,6-TRIIODOBENZENE;1,3,5-TRIFLUORO-2,4,6-TRIIODOBENZENE;1,3,5-Trifluoro-2,4,6-Triiodob;1,3,5-Trifluoro-2,4;Benzene,1,3,5-trifluoro-2,4,6-triiodo-
• CAS NO: 84322-56-5
• Molecular Formula: C₆F₃I₃
• Molecular Weight: 509.77
• Mol File: 84322-56-5.mol
• Article Data: 12

Chemical Properties

• Melting Point: 152℃
• Boiling Point: 352.4 °C at 760 mmHg
• Flash Point: 148.5 °C
• Appearance: /
• Density: 3.029 g/cm³
• Vapor Pressure: 7.82E-05mmHg at 25°C
• Refractive Index: 1.698
• Storage Temp.: 2-8°C(protect from light)
• Water Solubility: Slightly soluble in water.
• Sensitive: Light Sensitive
• CAS DataBase Reference: 1,3,5-Trifluoro-2,4,6-triiodobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-Trifluoro-2,4,6-triiodobenzene(84322-56-5)
• EPA Substance Registry System: 1,3,5-Trifluoro-2,4,6-triiodobenzene(84322-56-5)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 84322-56-5(Hazardous Substances Data)

Usage

Uses

1,3,5-Trifluoro-2,4,6-triiodobenzene is useful for biological applications. Further, it is used as an intermediate in organic synthesis.

InChI:InChI=1/C6F3I3/c7-1-4(10)2(8)6(12)3(9)5(1)11

Upstream product

• 506407-77-8 2,4,6-trifluoro-3,5-diiodophenyl radical 
• 506407-82-5 1,3-didehydro-2,4,6-trifluoro-5-iodobenzene 
• 372-38-3 1,3,5-trifluorobenzene 

Downstream Products

• 506407-72-3 2,4,6-trifluoro-1,3-diiodo-5-(trimethylsilyl)benzene 
• 674289-04-4 1,3,5-tris(phenylethynyl)-2,4,6-trifluorobenzene 
• 674289-03-3 ((2,4,6-trifluorobenzene-1,3,5-triyl)tris(ethyne-2,1-diyl))tris(trimethylsilane) 
• 204718-37-6 1,3,5-triiodo-2,4,6-trimethoxybenzene 
• 506407-77-8 2,4,6-trifluoro-3,5-diiodophenyl radical 
• 793684-41-0 (2,4,6-trimethoxybenzene-1,3,5-triyl)tris(ethyne-2,1-diyl)tris(trimethylsilane) 
• 793684-42-1 1,3,5-tris(ethynyl)-2,4,6-trimethoxybenzene 

Relevant articles and documents

Single-Crystal-to-Single-Crystal (SCSC) Linear Polymerization of a Desymmetrized Anthraphane

In this work we present one of the rare cases of single-crystal-to-single-crystal (SCSC) linear polymerizations, resulting in a novel ladder-type polymer. The polymerization is based on the photoinduced [4+4]-cycloaddition reactions between trifunctional

Connectivity and topology invariance in self-assembled and halogen-bonded anionic (6,3)-networks

We report here that the halogen bond driven self-assembly of 1,3,5-trifluorotriiodobenzene with tetraethylammonium and -phosphonium bromides affords 1:1 co-crystals, wherein the mutual induced fit of the triiodobenzene derivative and the bromide anions (halogen bond donor and acceptors, respectively) elicits the potential of these two tectons to function as tritopic modules (6,3). Supramolecular anionic networks are present in the two co-crystals wherein the donor and the acceptor alternate at the vertexes of the hexagonal frames and cations are accommodated in the potential empty space encircled by the frames. The change of one component in a self-assembled multi-component co-crystal often results in a change in its supramolecular connectivity and topology. Our systems have the same supramolecular features of corresponding iodide analogues as the metric aspects seem to prevail over other aspects in controlling the self-assembly process.

In situ generation and trapping of aryllithium and arylpotassium species by halogen, sulfur, and carbon electrophiles

(Chemical Equation Presented) A general method has been developed for in situ trapping of arylmetal intermediates by halogen, sulfur, ketone, and aldehyde electrophiles affording the functionalization of the most acidic position in arene. Pentafluorobenzene, benzothiazole, and benzoxazole can be functionalized by using K3PO4 base. For less acidic arenes, tBuOLi base is required. Arenes with DMSO pKa values of 35 or less are reactive. 2009 American Chemical Society.