506407-77-8

Upstream product

• 372-38-3 1,3,5-trifluorobenzene 
• 84322-56-5 1,3,5-trifluoro-2,4,6-triiodobenzene 

Downstream Products

• 506407-82-5 1,3-didehydro-2,4,6-trifluoro-5-iodobenzene 
• 946433-64-3 1,3,5-tridehydro-2,4,6-trifluorobenzene 
• 84322-56-5 1,3,5-trifluoro-2,4,6-triiodobenzene 

Relevant academic research and scientific papers

Trifluoro-1,3,5-tridehydrobenzene

(Chemical Equation Presented) Three stay, three go: Flash vacuum pyrolysis (FVP) of 1 and subsequent trapping of the products in solid argon at 3 K produces trifluoro-1,3,5-tridehydrobenzene (2). IR spectroscopy, the photochemical behavior, and quantum chemical calculations confirm that for the first time a derivative of the elusive 1,3,5-tridehydrobenzene could be isolated and spectroscopically characterized.

Generation of fluorinated m-benzyne derivatives in neon matrices

The fluorinated m-didehydrobenzenes 5-H-, 5-deuterio-, 5-(trifluoromethyl)-, 5-(trimethylsilyl)-, and 5-iodo-2,4,6-trifluoro-1,3-didehydrobenzene 6b-6f were generated by UV photolysis of the corresponding 1,3-diiodobenzene derivatives 4b-4f in solid neon