84342-14-3Relevant academic research and scientific papers
HOMOLYTIC TRANSFORMATIONS OF FLUORINE-CONTAINING ACETALS
Yakupov, I. S.,Germash, A. V.,Zlotskii, S. S.,Rakhmankulov, D. L.
, p. 1024 - 1028 (2007/10/02)
Study of the homolytic transformations which occur during the dissociation of di-tert-butyl peroxide in linear fluorine-containing acetals (derivatives of 2,2,3,3-tetrafluoropropanol and 2,2,3,3,4,4,5,5-octafluoropentanol) shows that the reactivity of the molecule of the fluorine containing acetal is determined mainly by the C-H bonds adjacent to the two oxygen atoms, and the products from the fragmentation of the obtained dialkoxyalkyl radicals are fluorinated esters and alkyl radicals.The abstraction of a hydrogen atom from the molecules of the oligomeric formalsH(CF2)n(OCH2)mOCH2(CF2)nH leads to the dialkoxyalkyl radicals, which undergo fragmentation at the C-H bonds at the β position to the radical center with the formation of oligomeric esters H(CF2)n(OCH2)iOC(O)H (i = 1...m).
