2,2,3,3-tetrafluoropropyl formate

Base Information

• Chemical Name: 2,2,3,3-tetrafluoropropyl formate
• CAS No.: 84342-14-3
• Molecular Formula: C₄H₄F₄O₂
• Molecular Weight: 160.068
• Mol file: 84342-14-3.mol

Synonyms:2,2,3,3-tetrafluoropropyl formate

Chemical Property of 2,2,3,3-tetrafluoropropyl formate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2,3,3-tetrafluoropropyl formate

There total 2 articles about 2,2,3,3-tetrafluoropropyl formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

pentakis(2,2,3,3-tetrafluoropropoxy)phosphorane (71879-02-2) + chloral (75-87-6) → phosphoric acid tris-(2,2,3,3-tetrafluoro-propyl ester) (563-10-0) + chloroform (67-66-3,8013-54-5) + 3-chloro-1,1,2,2-tetrafluoropropane (679-85-6) + 2,2,3,3-tetrafluoropropyl formate (84342-14-3)

Guidance literature:

at 180 ℃; for 6h; Yield given; autoclave;

Reference yield:

di(1,1,3-trihydroperfluoropropoxy)methane (6263-72-5) → 1,1,2,2-Tetrafluorpropan (40723-63-5) + 2,2,3,3-tetrafluoropropyl formate (84342-14-3)

Guidance literature:

With di-tert-butyl peroxide; In benzene; at 130 ℃; initial accumulation rates; var. fluorine-containing acetals;

upstream raw materials:

di(1,1,3-trihydroperfluoropropoxy)methane

pentakis(2,2,3,3-tetrafluoropropoxy)phosphorane

chloral

Refernces

• 1、 Shermolovich, Yu. G.,Kolesnikov, N. P.,Rozhkova, Z. Z.,Kashkin, A. V.,Bakhmutov, Yu. L.,Markovskii, L. N.. "ALKYLATION OF ALDEHYDES AND KETONES WITH PENTAKIS(αH,αH,ωH-POLYFLUOROALKOXY)PHOSPHORANES". . p. 2231 - 2235. Retrieved 2007/10/02.